In your case the PSU is a problem for 2 cards (in all honestly I'd even want a 750W or better) for the 7970 everyone is recommending you get instead of xfire the 6950's!
As for cards it comes down to what you want and what you can get for your current if you do want to upgrade to one of the better single card solutions.
750w should be enough for your 2x 6950s. I have a highly OC'd i7, and had 2 unlocked 6950s in CF for a few days and it ran well. I played some games with it with no problem other than heat. I know I was pushing my HX650 but it worked none the less. If I did stress testing on my stuff it probably would have crashed, but since you have a 750w, it should work fine.